2003, Vol.6, No.1, pp.568-571
On the basis of thermodynamical description of the
nonlinear overstretching of DNA molecule it is shown that the
force-deformation equation is similar to the van der Vaals
equation. The B-DNA to S-DNA transition is considered as the
stability breaking. The transition is described as the passage
from a stable branch of the force-deformation curve to another
stable branch of this curve. Position of the accompanied plateau
is determined by means of Maxwell ruly analogously to the case of
van der Vaals equation. The "critical'' point for the
overstretching DNA molecule is predicted.
Key words:
DNA, Elasticity, overstretching
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